How to center table in a page in the middle of numbered list?

You can insert the table in a block and set the width:

+ Step 1
  #block(width: 100%, figure(
    table(
      columns: (auto, auto),
      align: (left, right),
      stroke: 0.5pt,
      table.header([Reagent], [1X Volume (µL)]),
      [A], [12.5],
      [B], [2.5],
    ),
    caption: [Table1],
  )) <tbl>
+ Step2

Please see for more details How to make centralized formulae in enums - #2 by Andrew

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